全文获取类型
收费全文 | 1485篇 |
免费 | 75篇 |
国内免费 | 195篇 |
专业分类
化学 | 1444篇 |
晶体学 | 6篇 |
力学 | 8篇 |
综合类 | 3篇 |
数学 | 17篇 |
物理学 | 277篇 |
出版年
2023年 | 29篇 |
2022年 | 29篇 |
2021年 | 21篇 |
2020年 | 25篇 |
2019年 | 22篇 |
2018年 | 24篇 |
2017年 | 41篇 |
2016年 | 46篇 |
2015年 | 41篇 |
2014年 | 70篇 |
2013年 | 103篇 |
2012年 | 74篇 |
2011年 | 76篇 |
2010年 | 83篇 |
2009年 | 105篇 |
2008年 | 102篇 |
2007年 | 115篇 |
2006年 | 88篇 |
2005年 | 84篇 |
2004年 | 67篇 |
2003年 | 41篇 |
2002年 | 33篇 |
2001年 | 41篇 |
2000年 | 34篇 |
1999年 | 24篇 |
1998年 | 26篇 |
1997年 | 21篇 |
1996年 | 17篇 |
1995年 | 35篇 |
1994年 | 25篇 |
1993年 | 21篇 |
1992年 | 23篇 |
1991年 | 21篇 |
1990年 | 12篇 |
1989年 | 20篇 |
1988年 | 19篇 |
1987年 | 11篇 |
1986年 | 10篇 |
1985年 | 11篇 |
1984年 | 20篇 |
1983年 | 8篇 |
1982年 | 9篇 |
1981年 | 5篇 |
1980年 | 8篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1973年 | 3篇 |
排序方式: 共有1755条查询结果,搜索用时 31 毫秒
1.
《Current Applied Physics》2020,20(8):925-930
The well-known quaternary Cu2ZnSnS4 (CZTS) chalcogenide thin films are playing an important role in modern technology. The CZTS nanocrystal were successfully prepared by solution method using water, ethylene glycol and ethylenediamine as different solvent. The pure phase material was used for thin film coating by thermal evaporation method. The prepared CZTS thin films were characterized by XRD, Raman spectroscopy, FESEM, XPS and FT-IR spectroscopy. The XRD and Raman spectroscopy analysis revealed the formation of polycrystalline CZTS thin film with tetragonal crystal structure after annealing at 450 °C. The oxidation state of the annealed film was studied by XPS. A direct band gap about 1.36 eV was estimated for the film from FT-IR studies, which is nearly close to the optimum value of band gap energy of CZTS materials for best solar cell efficiency. The CZTS annealed thin films are more suitable for using as a p-type absorber layer in a low-cost solar cell. 相似文献
2.
Li-Ngee Ho Tasuku Ikegawa Hiroyasu Nishiguchi Katsutoshi Nagaoka Yusaku Takita 《Applied Surface Science》2006,252(18):6260-6268
A synthesis of molybdenum incorporated mesoporous aluminophosphate with long-chain n-alkylamine as template material had been prepared under non-aqueous condition. These materials were extensively characterized by using X-ray diffraction (XRD), nitrogen sorption isotherms, nuclear magnetic resonance of 27Al and 31P (NMR), inductive coupled plasma (ICP), electron spin resonance (ESR), Fourier transform infrared (FTIR) and thermogravimetric-differential thermal analysis (TG-DTA). Morphology of the materials had been observed by using transmission electron microscope (TEM) that revealed the mesoporous materials possessed wormhole-like structures. Alkaline solvent extraction using n-butylamine/ethanol had been efficiently removed the n-alkylamine from the mesoporous samples which yielded BET surface areas around 550-730 m2/g. BJH analysis showed a narrow pore size distribution which increased with increasing of the carbon chain length of alkylamine (template). Valence state and coordination of the molybdenum in the obtained samples were investigated by using ESR and FTIR where it was found that Mo4+ and Mo6+ molybdenum species existed in the molybdenum incorporated mesoporous aluminophosphate in tetrahedral coordination. 相似文献
3.
3-Hydroxy-4-hydroxymethyl pyrrolidin-2-ones, easily prepared from the Baylis–Hillman adduct 1-ethyl-4-methyl-2-hydroxy-3-methylenebutanedioate, are useful intermediates in the synthesis of bioactive compounds. In order to understand the mechanism involved in this reaction, vibrational and Montecarlo molecular mechanics conformational analysis on 1-ethyl-4-methyl-2-hydroxy-3-methylenebutanedioate were carried out, confirming the existence of a low energy intramolecular H-bonded five-member ring. 相似文献
4.
This work is aimed at the optimization of the yield and purity of non-symmetrical trialkyl sulfonium halide salts. The effects of parameters such as solvent, temperature and concentration were studied. The products were carefully analyzed and the crystal structure of [{n-CH3(CH2)15}(CH3)2S]Br determined. The overall aim of the present study is future syntheses of low-dimensional magnetic materials. 相似文献
5.
Transition from chaotic to ordered state has been observed during the initial stage of a discharge in a cylindrical DC glow
discharge plasma. Initially it shows a chaotic behavior but increasing the discharge voltage changes the characteristics of
the discharge glow and shows a period subtraction of order 7 period → 5 period → 3 period → 1 period, i.e. the system goes
to single mode through odd cycle subtraction. On further increasing the discharge voltage, the system goes through period
doubling, like 1 period → 2 period → 4 period. On further increasing the voltage, the system goes to stable state through
two period subtraction, like 4 period → 2 period → stable. 相似文献
6.
Capillary gas chromatography coupled to microwave-inducedplasma detection furnishes sensitivity adequate for trace analysis when the signal is monitored at a carbon emission line. Work performed with one of these systems at high electronic gain for the carbon signal has revealed solvent band widths in excess of four minutes; these impeded quantification of peaks eluting after the solvent. This report discusses two phenomena which could be related to the unexpected intensity of this solvent response: photomultiplier tube saturation and carbon deposits in the quartz plasma discharge tube. 相似文献
7.
本文就红外光谱中溶剂效应机理提出了溶质和溶剂分子间的瞬时配位作用机制,认为同-溶质在不同溶剂中的振动波数不同,是由于这种瞬时配位作用改变了溶质价电子运动状态所致。据此提出了溶剂效砂的定量关系式,测定了七种溶剂配位效应常数。用这一套经验参数处理了几种取代苯甲酸的羰基伸缩振动的溶剂效应,得较好的线性关系。还发现羰基的振动波数与取代基的Hammett常数σ之间,羰基伸缩振动对溶剂效应的敏感度与σ之间,H 相似文献
8.
We describe high order numerical algorithms for the solution of second order elliptic equations in rectangular domains. These
algorithms are based on the Fourier method in combination with a subtraction procedure. The singularities at the corner points,
arising due to non-smoothness of the boundaries, are treated explicitly using properly constructed singular corner functions.
The present algorithm is a generalization of the Fast Poisson Solver developed in our previous paper.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
9.
J.L. Shui 《Applied Surface Science》2006,253(5):2379-2385
Spongy-like reticular structure is a unique morphology fabricated by electrostatic spray deposition (ESD) technique. The effects of solvent, substrate temperature, precursor feeding rate, static electric field strength, and deposition time on tailoring the reticular structure were investigated. Scanning electron microscopy was used to observe the film morphology. MnOx or LiMn2O4 were selected as the model materials. It is found that in addition to the conventional solvent butyl carbitol, other kinds of solvents such as ethylene glycol and propylene glycol can also be used to obtain reticular films at a suitable substrate temperature. Porous films with a low cross-linking degree pore structure can be prepared by increasing precursor feeding rate or decreasing substrate temperature. Increasing the deposition time or the electric field strength helps to obtain reticular films with more homogeneous pore size distribution. In addition, the addition of a high boiling-point solvent in mixed alcohol solvent results in the increase of proper substrate temperature. It is concluded that the fluidity of the spray droplets on the surface of a hot substrate is an important factor to form a reticular film. 相似文献
10.
J. Fang 《Optics & Laser Technology》1991,23(6):349-352
A rotational mismatch of gratings is used to generate a fringe carrier of an in-plane moiré pattern so that specimen deformation shows itself in the form of modulation of the carrier frequency. As both the unmodulated and modulated carriers are the patterns without fringe-loop or fringe-connection, they are automatically numbered with monotonical increasing orders by a digital image processing system without any ambiguity. The orders at every pixel of the image are determined by interpolation of the orders of the tracked fringes to establish two grey image files, from the difference of which, the orders of the in-plane displacement moiré are displayed with grey-level variation. 相似文献